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Issue 64, 2014
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Tuning the electronic effects of aromatic phosphorus heterocycles: an unprecedented phosphinine with significant P(π)-donor properties

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Abstract

A hitherto unprecedented electronic situation has been observed for a substituted, pyridyl-functionalized phosphinine. In contrast to previous studies, this compound shows considerable π-donor properties as the result of the rather strong +M effect of the CH3S-substituent, changing the electronic properties of this low-coordinate and aromatic phosphorus heterocycle substantially.

Graphical abstract: Tuning the electronic effects of aromatic phosphorus heterocycles: an unprecedented phosphinine with significant P(π)-donor properties

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Publication details

The article was received on 08 May 2014, accepted on 06 Jun 2014 and first published on 09 Jun 2014


Article type: Communication
DOI: 10.1039/C4CC03469D
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 8842-8844
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    Tuning the electronic effects of aromatic phosphorus heterocycles: an unprecedented phosphinine with significant P(π)-donor properties

    A. Loibl, I. de Krom, E. A. Pidko, M. Weber, J. Wiecko and C. Müller, Chem. Commun., 2014, 50, 8842
    DOI: 10.1039/C4CC03469D

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