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Issue 64, 2014
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A cooperative Pd–Cu system for direct C–H bond arylation

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Abstract

A novel and efficient method for C–H arylation using well-defined Pd– and Cu–NHC systems has been developed. This process promotes the challenging construction of C–C bonds from arenes or heteroarenes using aryl bromides and chlorides. Mechanistic studies show that [Cu(OH)(NHC)] plays a key role in the C–H activation and is involved in the transmetallation with the Pd–NHC co-catalyst.

Graphical abstract: A cooperative Pd–Cu system for direct C–H bond arylation

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Publication details

The article was received on 29 Apr 2014, accepted on 20 Jun 2014 and first published on 30 Jun 2014


Article type: Communication
DOI: 10.1039/C4CC03201B
Citation: Chem. Commun., 2014,50, 8927-8929
  • Open access: Creative Commons BY license
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    A cooperative Pd–Cu system for direct C–H bond arylation

    M. Lesieur, F. Lazreg and C. S. J. Cazin, Chem. Commun., 2014, 50, 8927
    DOI: 10.1039/C4CC03201B

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