Issue 62, 2014
From the journal:

Chemical Communications

Palladium-catalyzed formal arylacylation of allenes employing acid chlorides and arylboronic acids†

Kenta Tatsumi,a   Tetsuaki Fujihara,*a   Jun Teraoa  and  Yasushi Tsuji*a  

* Corresponding authors

a Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan
E-mail: tfuji@scl.kyoto-u.ac.jp, ytsuji@scl.kyoto-u.ac.jp
Fax: +81-75-383-2514
Tel: +81-75-383-2515

Abstract

Palladium-catalyzed formal arylacylation of allenes using acid chlorides and arylboronic acids has been achieved. The reaction afforded the corresponding α,β-unsaturated ketones regio- and stereoselectively.

Graphical abstract: Palladium-catalyzed formal arylacylation of allenes employing acid chlorides and arylboronic acids

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Article information

DOI
https://doi.org/10.1039/C4CC03173C
Article type
Communication
Submitted
29 Apr 2014
Accepted
20 May 2014
First published
20 May 2014

Chem. Commun., 2014,50, 8476-8479

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Palladium-catalyzed formal arylacylation of allenes employing acid chlorides and arylboronic acids

K. Tatsumi, T. Fujihara, J. Terao and Y. Tsuji, Chem. Commun., 2014, 50, 8476 DOI: 10.1039/C4CC03173C

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