A luminescent heptanuclear DyIr6 complex showing field-induced slow magnetization relaxation

Dai Zeng; Min Ren; Song-Song Bao; Li Li; Li-Min Zheng

doi:10.1039/C4CC02951H

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A luminescent heptanuclear DyIr₆ complex showing field-induced slow magnetization relaxation†‡

Dai Zeng,^a Min Ren,^a Song-Song Bao,^a Li Li^a and Li-Min Zheng*^a

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* Corresponding authors

^a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China
E-mail: lmzheng@nju.edu.cn
Fax: +86-25-83314502

Abstract

The first example of iridium/lanthanide phosphonates, i.e. [DyIr₆(ppy)₁₂(bpp)₂(bppH)₄](CF₃SO₃)·8H₂O (1) (ppy⁻ = 2-phenylpyridine, bpp²⁻ = 2-pyridylphosphonate) is reported. It shows dual functions with the photoluminescence and field-induced slow magnetization relaxation originating from the Ir and Dy moieties, respectively.

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Article information

DOI: https://doi.org/10.1039/C4CC02951H
Article type: Communication
Submitted: 21 Apr 2014
Accepted: 05 Jun 2014
First published: 11 Jun 2014

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Chem. Commun., 2014,50, 8356-8359

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A luminescent heptanuclear DyIr₆ complex showing field-induced slow magnetization relaxation

D. Zeng, M. Ren, S. Bao, L. Li and L. Zheng, Chem. Commun., 2014, 50, 8356 DOI: 10.1039/C4CC02951H

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Chemical Communications