Issue 65, 2014

Discrete and encapsulated molecular grids: homometallic Mn15 and heterometallic Mn24Ni2 aggregates

Abstract

Two molecular grid-like clusters are reported, one is a discrete [3 × 5] grid and the other a [3 × 4] grid within a Mn12Ni2 loop. Both Mn24Ni2 and Mn15 aggregates display novel and aesthetically pleasing structures with the former one being among the highest nuclearity heterometallic MnxMy clusters (M = any transition metal ion).

Graphical abstract: Discrete and encapsulated molecular grids: homometallic Mn15 and heterometallic Mn24Ni2 aggregates

Supplementary files

Article information

Article type
Communication
Submitted
18 Apr 2014
Accepted
20 Jun 2014
First published
20 Jun 2014

Chem. Commun., 2014,50, 9090-9093

Author version available

Discrete and encapsulated molecular grids: homometallic Mn15 and heterometallic Mn24Ni2 aggregates

M. Charalambous, S. M. Zartilas, E. E. Moushi, C. Papatriantafyllopoulou, M. J. Manos, T. C. Stamatatos, S. Mukherjee, V. Nastopoulos, G. Christou and A. J. Tasiopoulos, Chem. Commun., 2014, 50, 9090 DOI: 10.1039/C4CC02893G

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