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Issue 64, 2014
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Regioselective hydrations of 1-aryl-3-en-1-ynes using gold and platinum catalysts: selective production of 2-en-1-ones and 3-en-1-ones

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Abstract

Regiocontrolled hydrations of 1-aryl-3-en-1-ynes have been accomplished with IPrAuOTf and PtCl2/CO to yield 3-en-1-ones and 2-en-1-ones efficiently; our experimental data indicates that the sizes of catalysts play an important role.

Graphical abstract: Regioselective hydrations of 1-aryl-3-en-1-ynes using gold and platinum catalysts: selective production of 2-en-1-ones and 3-en-1-ones

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Publication details

The article was received on 15 Apr 2014, accepted on 18 Jun 2014 and first published on 18 Jun 2014


Article type: Communication
DOI: 10.1039/C4CC02786H
Citation: Chem. Commun., 2014,50, 8966-8969
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    Regioselective hydrations of 1-aryl-3-en-1-ynes using gold and platinum catalysts: selective production of 2-en-1-ones and 3-en-1-ones

    B. D. Mokar and R. Liu, Chem. Commun., 2014, 50, 8966
    DOI: 10.1039/C4CC02786H

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