Issue 64, 2014
From the journal:

Chemical Communications

Regioselective hydrations of 1-aryl-3-en-1-ynes using gold and platinum catalysts: selective production of 2-en-1-ones and 3-en-1-ones†

Bhanudas Dattatray Mokara  and  Rai-Shung Liu*a  

* Corresponding authors

a National Tsing Hua University, Hsinchu, Taiwan
E-mail: rsliu@mx.nthu.edu.tw

Abstract

Regiocontrolled hydrations of 1-aryl-3-en-1-ynes have been accomplished with IPrAuOTf and PtCl2/CO to yield 3-en-1-ones and 2-en-1-ones efficiently; our experimental data indicates that the sizes of catalysts play an important role.

Graphical abstract: Regioselective hydrations of 1-aryl-3-en-1-ynes using gold and platinum catalysts: selective production of 2-en-1-ones and 3-en-1-ones

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Article information

DOI
https://doi.org/10.1039/C4CC02786H
Article type
Communication
Submitted
15 Apr 2014
Accepted
18 Jun 2014
First published
18 Jun 2014

Chem. Commun., 2014,50, 8966-8969

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Regioselective hydrations of 1-aryl-3-en-1-ynes using gold and platinum catalysts: selective production of 2-en-1-ones and 3-en-1-ones

B. D. Mokar and R. Liu, Chem. Commun., 2014, 50, 8966 DOI: 10.1039/C4CC02786H

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