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Issue 57, 2014
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On-surface Ullmann polymerization via intermediate organometallic networks on Ag(111)

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Abstract

The role of organometallic intermediates during on-surface polymerization via Ullmann coupling was studied on Ag(111). The polymerization progress was monitored by X-ray photoelectron spectroscopy (XPS). Scanning Tunneling Microscopy (STM) was used to characterize organometallic and covalent networks and to identify the temperature regimes for organometallic and covalent bond formation.

Graphical abstract: On-surface Ullmann polymerization via intermediate organometallic networks on Ag(111)

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Publication details

The article was received on 14 Apr 2014, accepted on 19 May 2014 and first published on 21 May 2014


Article type: Communication
DOI: 10.1039/C4CC02757D
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Citation: Chem. Commun., 2014,50, 7680-7682
  • Open access: Creative Commons BY license
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    On-surface Ullmann polymerization via intermediate organometallic networks on Ag(111)

    J. Eichhorn, T. Strunskus, A. Rastgoo-Lahrood, D. Samanta, M. Schmittel and M. Lackinger, Chem. Commun., 2014, 50, 7680
    DOI: 10.1039/C4CC02757D

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