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Issue 53, 2014
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Selective P4 activation by an organometallic nickel(I) radical: formation of a dinuclear nickel(II) tetraphosphide and related di- and trichalcogenides

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Abstract

The reaction of the 17e nickel(I) radical [CpNi(IDipp)] (1, IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) with P4 results in a nickel tetraphosphide [{CpNi(IDipp)}2(μ-η11-P4)] with a butterfly-P42− ligand; related chalcogenides [{CpNi(IDipp)}2(μ-E2)] (E = S, Se, Te) and [{CpNi(IDipp)}2(μ-E3)] (E = S, Se) are formed with S8, Se and Te.

Graphical abstract: Selective P4 activation by an organometallic nickel(i) radical: formation of a dinuclear nickel(ii) tetraphosphide and related di- and trichalcogenides

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Publication details

The article was received on 08 Apr 2014, accepted on 14 May 2014 and first published on 14 May 2014


Article type: Communication
DOI: 10.1039/C4CC02601B
Citation: Chem. Commun., 2014,50, 7014-7016
  • Open access: Creative Commons BY-NC license
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    Selective P4 activation by an organometallic nickel(I) radical: formation of a dinuclear nickel(II) tetraphosphide and related di- and trichalcogenides

    S. Pelties, D. Herrmann, B. de Bruin, F. Hartl and R. Wolf, Chem. Commun., 2014, 50, 7014
    DOI: 10.1039/C4CC02601B

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