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Issue 61, 2014
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Bromide-bridged palladium(III) chain complexes showing charge bistability near room temperature

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Abstract

We synthesized and characterized bromide-bridged Pd(III) chain complexes, [Pd(en)2Br](MalCn–Y)2·H2O (en = ethylenediamine; MalCn–Y = dialkyl sulfomalonate; n: the number of carbon atoms) (n = 7 and 12). The compound with n = 7 showed charge-bistability near room temperature. In addition, it is shown that the Pd(III) state is maintained in the thin film state.

Graphical abstract: Bromide-bridged palladium(iii) chain complexes showing charge bistability near room temperature

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Publication details

The article was received on 07 Apr 2014, accepted on 05 Jun 2014 and first published on 19 Jun 2014


Article type: Communication
DOI: 10.1039/C4CC02547D
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 8382-8384
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    Bromide-bridged palladium(III) chain complexes showing charge bistability near room temperature

    S. Kumagai, S. Takaishi, B. K. Breedlove, H. Okamoto, H. Tanaka, S. Kuroda and M. Yamashita, Chem. Commun., 2014, 50, 8382
    DOI: 10.1039/C4CC02547D

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