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Issue 46, 2014
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Synthesis of alkylidene pyrrolo[3,4-b]pyridin-7-one derivatives via RhIII-catalyzed cascade oxidative alkenylation/annulation of picolinamides

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Abstract

A practical RhIII-catalyzed cascade olefination/annulation of picolinamides leading to pyrrolo[3,4-b]pyridines has been developed. The reaction shows wide scope, complete regiocontrol and excellent stereoselectivity.

Graphical abstract: Synthesis of alkylidene pyrrolo[3,4-b]pyridin-7-one derivatives via RhIII-catalyzed cascade oxidative alkenylation/annulation of picolinamides

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Publication details

The article was received on 28 Mar 2014, accepted on 15 Apr 2014 and first published on 16 Apr 2014


Article type: Communication
DOI: 10.1039/C4CC02322F
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 6105-6107
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    Synthesis of alkylidene pyrrolo[3,4-b]pyridin-7-one derivatives via RhIII-catalyzed cascade oxidative alkenylation/annulation of picolinamides

    Á. M. Martínez, N. Rodríguez, R. Gómez Arrayás and J. C. Carretero, Chem. Commun., 2014, 50, 6105
    DOI: 10.1039/C4CC02322F

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