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Issue 54, 2014
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Intramolecular N–H⋯Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl2 complex

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Abstract

A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl2 complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography.

Graphical abstract: Intramolecular N–H⋯Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl2 complex

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Publication details

The article was received on 28 Mar 2014, accepted on 14 May 2014 and first published on 15 May 2014


Article type: Communication
DOI: 10.1039/C4CC02297A
Citation: Chem. Commun., 2014,50, 7173-7175
  • Open access: Creative Commons BY-NC license
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    Intramolecular N–H⋯Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl2 complex

    J. V. Gavette, C. M. Klug, L. N. Zakharov, M. P. Shores, M. M. Haley and D. W. Johnson, Chem. Commun., 2014, 50, 7173
    DOI: 10.1039/C4CC02297A

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