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Issue 60, 2014
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Ordered alignment of a one-dimensional π-conjugated nickel bis(dithiolene) complex polymer produced via interfacial reactions

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Abstract

A liquid–liquid interfacial synthesis using 1,2,4,5-benzenetetrathiol and nickel(II) ions produced a thin black film of a π-conjugated polymer featuring the nickel bis(dithiolene) motif. Its ordered structure was not originally identified due to its amorphicity; however, it was observed to align regularly on a highly oriented pyrolytic graphite substrate using scanning tunnelling microscopy.

Graphical abstract: Ordered alignment of a one-dimensional π-conjugated nickel bis(dithiolene) complex polymer produced via interfacial reactions

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Publication details

The article was received on 18 Mar 2014, accepted on 14 Apr 2014 and first published on 15 Apr 2014


Article type: Communication
DOI: 10.1039/C4CC02022G
Citation: Chem. Commun., 2014,50, 8137-8139
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    Ordered alignment of a one-dimensional π-conjugated nickel bis(dithiolene) complex polymer produced via interfacial reactions

    R. Matsuoka, R. Sakamoto, T. Kambe, K. Takada, T. Kusamoto and H. Nishihara, Chem. Commun., 2014, 50, 8137
    DOI: 10.1039/C4CC02022G

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