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Issue 43, 2014
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Total synthesis of (+)-kopsihainanine A

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Total synthesis of (+)-kopsihainanine A was accomplished on the basis of (i) Stoltz's enantioselective decarboxylative asymmetric allylation and (ii) the proposed biogenetic pathway from the related alkaloid, kopsihainanine B. In addition, HPLC analysis of the synthetic (+)-kopsihainanine A confirmed its ee to be 99% with [α]30D = 25.35.

Graphical abstract: Total synthesis of (+)-kopsihainanine A

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The article was received on 12 Mar 2014, accepted on 14 Apr 2014 and first published on 14 Apr 2014

Article type: Communication
DOI: 10.1039/C4CC01843E
Citation: Chem. Commun., 2014,50, 5782-5785
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    Total synthesis of (+)-kopsihainanine A

    M. Mizutani, S. Yasuda and C. Mukai, Chem. Commun., 2014, 50, 5782
    DOI: 10.1039/C4CC01843E

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