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Issue 43, 2014
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Novel tartrate-derived guanidine-catalyzed highly enantio- and diastereoselective Michael addition of 3-substituted oxindoles to nitroolefins

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Abstract

The Michael addition of 3-substituted oxindoles to nitroolefins was catalyzed by a novel tartrate-derived guanidine in high yield with excellent diastereo- and enantioselectivity. This method showed an extraordinarily broad substrate scope in terms of both reaction partners.

Graphical abstract: Novel tartrate-derived guanidine-catalyzed highly enantio- and diastereoselective Michael addition of 3-substituted oxindoles to nitroolefins

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Publication details

The article was received on 11 Mar 2014, accepted on 04 Apr 2014 and first published on 08 Apr 2014


Article type: Communication
DOI: 10.1039/C4CC01817F
Citation: Chem. Commun., 2014,50, 5760-5762
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    Novel tartrate-derived guanidine-catalyzed highly enantio- and diastereoselective Michael addition of 3-substituted oxindoles to nitroolefins

    L. Zou, X. Bao, Y. Ma, Y. Song, J. Qu and B. Wang, Chem. Commun., 2014, 50, 5760
    DOI: 10.1039/C4CC01817F

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