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Issue 37, 2014
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A robust, catalytic metal–organic framework with open 2,2′-bipyridine sites

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Abstract

We report two synthetic approaches to prepare a highly crystalline Zr(IV)-based metal–organic framework (MOF) containing open 2,2′-bipyridine (bpy) chelating sites. The resulting UiO-67-bpydc readily forms complexes with PdCl2 to produce a MOF that exhibits efficient and recyclable catalytic activity for the Suzuki–Miyaura cross-coupling reaction.

Graphical abstract: A robust, catalytic metal–organic framework with open 2,2′-bipyridine sites

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Publication details

The article was received on 03 Mar 2014, accepted on 19 Mar 2014 and first published on 21 Mar 2014


Article type: Communication
DOI: 10.1039/C4CC01607F
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 4810-4812
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    A robust, catalytic metal–organic framework with open 2,2′-bipyridine sites

    H. Fei and S. M. Cohen, Chem. Commun., 2014, 50, 4810
    DOI: 10.1039/C4CC01607F

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