Issue 42, 2014

Efficient and exceptionally selective semireduction of alkynes using a supported gold catalyst under a CO atmosphere

Abstract

A new efficient method for chemo- and regio-selective semireduction of alkynes using CO/H2O as the hydrogen source catalyzed by gold supported on high surface area TiO2 was developed. A facile and practical synthesis of 1,2-dideuterioalkenes was also realized by using CO/D2O as the reducing agent.

Graphical abstract: Efficient and exceptionally selective semireduction of alkynes using a supported gold catalyst under a CO atmosphere

Supplementary files

Article information

Article type
Communication
Submitted
03 Mar 2014
Accepted
25 Mar 2014
First published
04 Apr 2014

Chem. Commun., 2014,50, 5626-5628

Efficient and exceptionally selective semireduction of alkynes using a supported gold catalyst under a CO atmosphere

S. Li, X. Liu, Y. Liu, H. He, K. Fan and Y. Cao, Chem. Commun., 2014, 50, 5626 DOI: 10.1039/C4CC01595A

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