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Issue 41, 2014
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Use of solvent to regulate the degree of polymerisation in weakly associated supramolecular oligomers

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Abstract

Using a tetrathiafulvalene functionalised calix[4]pyrrole (TTF-C[4]P; 1) and alkyl diester-linked bis-dinitrophenols (2–4), it was found that the solvent polarity and linker length have an effect on the molecular aggregation behaviour. 2D 1H NOESY, DOSY NMR and UV-vis-NIR spectroscopic studies, as well as single crystal X-ray diffraction analyses support these conclusions.

Graphical abstract: Use of solvent to regulate the degree of polymerisation in weakly associated supramolecular oligomers

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Publication details

The article was received on 27 Feb 2014, accepted on 02 Apr 2014, published on 02 Apr 2014 and first published online on 02 Apr 2014


Article type: Communication
DOI: 10.1039/C4CC01514B
Citation: Chem. Commun., 2014,50, 5497-5499
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    Use of solvent to regulate the degree of polymerisation in weakly associated supramolecular oligomers

    S. Bähring, D. S. Kim, T. Duedal, V. M. Lynch, K. A. Nielsen, J. O. Jeppesen and J. L. Sessler, Chem. Commun., 2014, 50, 5497
    DOI: 10.1039/C4CC01514B

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