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Issue 51, 2014
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Connection of zinc paddle-wheels in a pto-type metal–organic framework with 2-methylimidazolate and subsequent incorporation of charged organic guests

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Abstract

A microporous metal–organic framework (mIm-MOF-14) has doubly interpenetrated anionic frameworks resulting from 2-methylimidazolate linking Zn(II) paddle-wheels of charge-neutral pto-type networks, and allows the inclusion of tetramethylammonium ion to exert an enhanced CO2 affinity.

Graphical abstract: Connection of zinc paddle-wheels in a pto-type metal–organic framework with 2-methylimidazolate and subsequent incorporation of charged organic guests

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Publication details

The article was received on 27 Feb 2014, accepted on 10 May 2014 and first published on 12 May 2014


Article type: Communication
DOI: 10.1039/C4CC01501K
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Citation: Chem. Commun., 2014,50, 6785-6788
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    Connection of zinc paddle-wheels in a pto-type metal–organic framework with 2-methylimidazolate and subsequent incorporation of charged organic guests

    N. Ko, K. Noh, S. Sung, H. J. Park, S. Y. Park and J. Kim, Chem. Commun., 2014, 50, 6785
    DOI: 10.1039/C4CC01501K

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