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Issue 42, 2014
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A preferable molecular crystal membrane for H2 gas separation

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Abstract

A novel molecular crystal membrane [Cu(II)2(9-AC)4(pyz)]n (9-AC: 9-anthracenecarboxylate, pyz: pyrazine) shows high permselectivity for H2/CO (79.0), H2/CH4 (137), and H2/CO2 (12.1) due to the high rate of H2 permeation (3820 Barrer) while inhibiting the permeation of such a large gaseous particle even in its wider channel than the Lennard-Jones diameter of each gas.

Graphical abstract: A preferable molecular crystal membrane for H2 gas separation

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Publication details

The article was received on 27 Feb 2014, accepted on 04 Apr 2014 and first published on 04 Apr 2014


Article type: Communication
DOI: 10.1039/C4CC01494D
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 5662-5664
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    A preferable molecular crystal membrane for H2 gas separation

    Y. Takasaki and S. Takamizawa, Chem. Commun., 2014, 50, 5662
    DOI: 10.1039/C4CC01494D

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