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Issue 74, 2014
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AgNO2-mediated direct nitration of the quinoxaline tertiary benzylic C–H bond and direct conversion of 2-methyl quinoxalines into related nitriles

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Abstract

A unique method for AgNO2-mediated direct nitration of the quinoxaline tertiary C–H bond and direct conversion of 2-methyl quinoxalines into 2-quinoxaline nitriles under oxidative conditions has been developed. This protocol provides an efficient way to access quinoxaline containing nitroalkanes and nitriles depending on different substrate selection.

Graphical abstract: AgNO2-mediated direct nitration of the quinoxaline tertiary benzylic C–H bond and direct conversion of 2-methyl quinoxalines into related nitriles

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Publication details

The article was received on 20 Feb 2014, accepted on 21 Jul 2014 and first published on 25 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC01327A
Citation: Chem. Commun., 2014,50, 10857-10860
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    AgNO2-mediated direct nitration of the quinoxaline tertiary benzylic C–H bond and direct conversion of 2-methyl quinoxalines into related nitriles

    D. Wu, J. Zhang, J. Cui, W. Zhang and Y. Liu, Chem. Commun., 2014, 50, 10857
    DOI: 10.1039/C4CC01327A

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