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Issue 63, 2014
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Structure–kinetic relationship study of organozinc reagents

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Abstract

Phenylzinc reagents prepared from various zinc halides show distinct kinetic features in the palladium-catalyzed Negishi-type oxidative coupling reaction, in which the phenylzinc reagent prepared from ZnI2 gives the highest rate. In situ infrared and X-ray absorption spectroscopy studies show that the higher reaction rate was observed for longer Zn–C bond distances.

Graphical abstract: Structure–kinetic relationship study of organozinc reagents

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Publication details

The article was received on 12 Feb 2014, accepted on 16 May 2014 and first published on 16 May 2014


Article type: Communication
DOI: 10.1039/C4CC01135J
Citation: Chem. Commun., 2014,50, 8709-8711
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    Structure–kinetic relationship study of organozinc reagents

    G. Zhang, J. Li, Y. Deng, J. T. Miller, A. J. Kropf, E. E. Bunel and A. Lei, Chem. Commun., 2014, 50, 8709
    DOI: 10.1039/C4CC01135J

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