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Issue 47, 2014
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Alkyl transfer from C–C cleavage: replacing the nitro group of nitro-olefins

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Abstract

Alkyl substituted Hantzsch esters are rationally used as alkylation reagents to replace the nitro groups of nitro olefins to give excellent yields of trans-olefins. The reaction mechanism is considered to proceed through a free radical mechanism, which is different from the corresponding transfer alkylation of imines.

Graphical abstract: Alkyl transfer from C–C cleavage: replacing the nitro group of nitro-olefins

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Publication details

The article was received on 12 Feb 2014, accepted on 17 Mar 2014 and first published on 17 Mar 2014


Article type: Communication
DOI: 10.1039/C4CC01119H
Citation: Chem. Commun., 2014,50, 6246-6248
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    Alkyl transfer from C–C cleavage: replacing the nitro group of nitro-olefins

    G. Li, L. Wu, G. Lv, H. Liu, Q. Fu, X. Zhang and Z. Tang, Chem. Commun., 2014, 50, 6246
    DOI: 10.1039/C4CC01119H

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