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Issue 43, 2014
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Phosphine-catalyzed sequential annulation domino reaction: rapid construction of bicyclo[4.1.0]heptene skeletons

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Abstract

A convenient and efficient phosphine-catalyzed sequential annulation domino reaction between dienic sulfones and MBH carbonates has been developed. In the presence of 20 mol% of tris(4-fluorophenyl)phosphine, functionalized bicyclo[4.1.0]heptenes were prepared in excellent yields and stereoselectivities under mild conditions.

Graphical abstract: Phosphine-catalyzed sequential annulation domino reaction: rapid construction of bicyclo[4.1.0]heptene skeletons

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Publication details

The article was received on 11 Feb 2014, accepted on 02 Apr 2014 and first published on 03 Apr 2014


Article type: Communication
DOI: 10.1039/C4CC01097C
Citation: Chem. Commun., 2014,50, 5710-5713
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    Phosphine-catalyzed sequential annulation domino reaction: rapid construction of bicyclo[4.1.0]heptene skeletons

    J. Zheng, Y. Huang and Z. Li, Chem. Commun., 2014, 50, 5710
    DOI: 10.1039/C4CC01097C

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