Self-assembly of a neutral platinum(II) complex into highly emitting microcrystalline fibers through metallophilic interactions

Matteo Mauro; Alessandro Aliprandi; Cristina Cebrián; Di Wang; Christian Kübel; Luisa De Cola

doi:10.1039/C4CC01045K

Self-assembly of a neutral platinum(II) complex into highly emitting microcrystalline fibers through metallophilic interactions

Matteo Mauro,*^a^b Alessandro Aliprandi,^a Cristina Cebrián,^a Di Wang,^c Christian Kübel^c and Luisa De Cola*^a^c

* Corresponding authors

^a ISIS & icFRC, Université de Strasbourg & CNRS, 8 rue Gaspard Monge, 67000 Strasbourg, France
E-mail: mauro@unistra.fr, decola@unistra.fr
Fax: +33 (0)3 6885 5242
Tel: +33 (0)3 6885 5220

^b University of Strasbourg Institute for Advanced Study (USIAS), 5 allée du Général Rouvillois, 67083 Strasbourg, France

^c Institute of Nanotechnology and Karlsruhe Nano Micro Facility, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz Platz 1, Eggenstein-Leopoldshafen, Germany

Abstract

The solvent-assisted self-assembly of a blue-emitting neutral platinum(II) complex into micrometer-long and highly crystalline fibers has been achieved. The aggregates show highly efficient (quantum yield up to 74%) polarized yellow-orange light emission, as a consequence of their high degree of supramolecular order imparted by weak non-covalent intermolecular (metal⋯metal and π–π) interactions.

Supplementary files

Publication details

The article was received on 09 Feb 2014, accepted on 07 May 2014 and first published on 07 May 2014

Article type: Communication

DOI: 10.1039/C4CC01045K

Author version available: Download Author version (PDF)

Citation: Chem. Commun., 2014,50, 7269-7272

Request permissions
Self-assembly of a neutral platinum(II) complex into highly emitting microcrystalline fibers through metallophilic interactions

M. Mauro, A. Aliprandi, C. Cebrián, D. Wang, C. Kübel and L. De Cola, Chem. Commun., 2014, 50, 7269
DOI: 10.1039/C4CC01045K
If you are not the author of this article and you wish to reproduce material from it in a third party non-RSC publication you must formally request permission using RightsLink. Go to our Instructions for using RightsLink page for details.

Authors contributing to RSC publications (journal articles, books or book chapters) do not need to formally request permission to reproduce material contained in this article provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:
For reproduction of material from NJC:
Reproduced from Ref. XX with permission from the Centre National de la Recherche Scientifique (CNRS) and The Royal Society of Chemistry.

For reproduction of material from PCCP:
Reproduced from Ref. XX with permission from the PCCP Owner Societies.

For reproduction of material from PPS:
Reproduced from Ref. XX with permission from the European Society for Photobiology, the European Photochemistry Association, and The Royal Society of Chemistry.

For reproduction of material from all other RSC journals and books:
Reproduced from Ref. XX with permission from The Royal Society of Chemistry.
If the material has been adapted instead of reproduced from the original RSC publication "Reproduced from" can be substituted with "Adapted from".

In all cases the Ref. XX is the XXth reference in the list of references.

If you are the author of this article you do not need to formally request permission to reproduce figures, diagrams etc. contained in this article in third party publications or in a thesis or dissertation provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:
For reproduction of material from NJC:
[Original citation] - Reproduced by permission of The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC

For reproduction of material from PCCP:
[Original citation] - Reproduced by permission of the PCCP Owner Societies

For reproduction of material from PPS:
[Original citation] - Reproduced by permission of The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC

For reproduction of material from all other RSC journals:
[Original citation] - Reproduced by permission of The Royal Society of Chemistry
If you are the author of this article you still need to obtain permission to reproduce the whole article in a third party publication with the exception of reproduction of the whole article in a thesis or dissertation.

Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Chemical Communications

Self-assembly of a neutral platinum(II) complex into highly emitting microcrystalline fibers through metallophilic interactions

Abstract

Supplementary files

Publication details

Self-assembly of a neutral platinum(II) complex into highly emitting microcrystalline fibers through metallophilic interactions

Search articles by author

Spotlight

Advertisements