Jump to main content
Jump to site search

Issue 31, 2014
Previous Article Next Article

Stereospecific conversion of alcohols into pinacol boronic esters using lithiation–borylation methodology with pinacolborane

Author affiliations

Abstract

The synthesis of primary and secondary pinacol boronic esters via lithiation–borylation of carbamates and benzoates with pinacolborane is described. This new protocol enables the highly selective synthesis of enantioenriched and geometrically defined boronic esters that cannot otherwise be accessed by alternative methodologies.

Graphical abstract: Stereospecific conversion of alcohols into pinacol boronic esters using lithiation–borylation methodology with pinacolborane

Back to tab navigation

Supplementary files

Publication details

The article was received on 06 Feb 2014, accepted on 26 Feb 2014 and first published on 26 Feb 2014


Article type: Communication
DOI: 10.1039/C4CC00993B
Citation: Chem. Commun., 2014,50, 4053-4055
  • Open access: Creative Commons BY license
  •   Request permissions

    Stereospecific conversion of alcohols into pinacol boronic esters using lithiation–borylation methodology with pinacolborane

    S. Roesner, C. A. Brown, M. Mohiti, A. P. Pulis, R. Rasappan, D. J. Blair, S. Essafi, D. Leonori and V. K. Aggarwal, Chem. Commun., 2014, 50, 4053
    DOI: 10.1039/C4CC00993B

    This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements