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Issue 37, 2014
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The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N]+·e as an electron donor

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Abstract

The scalable pinacol coupling reaction is realized utilizing the inorganic electride [Ca2N]+·e as an electron donor in organic solvents. The bond cleavages of the [Ca2N]+ layers by methanol play a vital role in transferring anionic electrons to electrophilic aldehydes, accompanying the formation of Ca(OMe)2 and ammonia.

Graphical abstract: The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N]+·e− as an electron donor

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Publication details

The article was received on 29 Jan 2014, accepted on 18 Mar 2014 and first published on 18 Mar 2014


Article type: Communication
DOI: 10.1039/C4CC00802B
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 4791-4794
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    The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N]+·e as an electron donor

    Y. J. Kim, S. M. Kim, H. Hosono, J. W. Yang and S. W. Kim, Chem. Commun., 2014, 50, 4791
    DOI: 10.1039/C4CC00802B

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