Issue 30, 2014

Layered structures and nanosheets of pyrimidinethiolate coordination polymers

Abstract

We report the synthesis, crystal structure and exfoliation of a new member of an important family of layered compounds: lamellar pyrimidinethiolate coordination polymers. Conductivity measurements and DFT calculations of iron(II) pyrimidine-2-thiolate show that this material and a related compound are insulators.

Graphical abstract: Layered structures and nanosheets of pyrimidinethiolate coordination polymers

Supplementary files

Article information

Article type
Communication
Submitted
28 Jan 2014
Accepted
27 Feb 2014
First published
27 Feb 2014

Chem. Commun., 2014,50, 3955-3957

Author version available

Layered structures and nanosheets of pyrimidinethiolate coordination polymers

P. J. Beldon, S. Tominaka, P. Singh, T. Saha Dasgupta, E. G. Bithell and A. K. Cheetham, Chem. Commun., 2014, 50, 3955 DOI: 10.1039/C4CC00771A

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