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Issue 54, 2014
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A stable metallic state of (TTPCOO)2NH4 with a mobile dopant

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Abstract

Ammonium tetrathiapentalene carboxylate [(TTPCOO)2NH4] was prepared via protonic defect-induction doping without electrochemical oxidation. The high electric conductivity of 13 S cm−1 and Pauli paramagnetic-like behavior of magnetic susceptibility in a wide temperature range exhibit a melting of the charge degrees of freedom induced by a mobile dopant in a salt bridge. Solid-state 1H NMR strongly indicates a stable metallic state of this compound down to 4 K.

Graphical abstract: A stable metallic state of (TTPCOO)2NH4 with a mobile dopant

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Publication details

The article was received on 27 Jan 2014, accepted on 13 Mar 2014 and first published on 27 Mar 2014


Article type: Communication
DOI: 10.1039/C4CC00678J
Citation: Chem. Commun., 2014,50, 7111-7113
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    A stable metallic state of (TTPCOO)2NH4 with a mobile dopant

    T. Terauchi, S. Sumi, Y. Kobayashi, T. Nakamura, K. Furukawa and Y. Misaki, Chem. Commun., 2014, 50, 7111
    DOI: 10.1039/C4CC00678J

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