Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Tuesday 19th September 2017 from 8.00am to 4.00pm (BST).

During this time our website performance may be temporarily affected. If you have any questions please use the feedback button available under our menu button. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 34, 2014
Previous Article Next Article

Revealing the metal-like behavior of iodine: an iodide-catalysed radical oxidative alkenylation

Author affiliations

Abstract

In this work, we have described an alternative alkenylation approach to illustrate the metal-like behaviour of iodine in cross-coupling reactions. Alkenylation could proceed through iodide catalysed radical initiation, radical addition and iodine promoted alkenyl functionality recovery. Catalytic HI elimination similar to the β-hydride elimination of transition metals was realized for the radical alkenylation of sulfonyl hydrazides. Operando IR and cyclic voltammetry experiments were carried out to confirm the crucial role of iodine in the radical alkenylation process.

Graphical abstract: Revealing the metal-like behavior of iodine: an iodide-catalysed radical oxidative alkenylation

Back to tab navigation

Supplementary files

Publication details

The article was received on 24 Jan 2014, accepted on 28 Feb 2014 and first published on 28 Feb 2014


Article type: Communication
DOI: 10.1039/C4CC00644E
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 4496-4499
  •   Request permissions

    Revealing the metal-like behavior of iodine: an iodide-catalysed radical oxidative alkenylation

    S. Tang, Y. Wu, W. Liao, R. Bai, C. Liu and A. Lei, Chem. Commun., 2014, 50, 4496
    DOI: 10.1039/C4CC00644E

Search articles by author

Spotlight

Advertisements