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Issue 31, 2014
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Stereospecific hydrodehalogenation of alkenyl bromides: a new approach to the synthesis of (E)-alkenes

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Abstract

The pair NaBH4–TMEDA and catalytic PdCl2(PPh3)2 in THF at room temperature is a mild and efficient system for the hydrodebromination of alkenyl bromides, providing a facile reduction procedure that allows completing the process advantageously, leading from aldehydes to (E)-alkenes.

Graphical abstract: Stereospecific hydrodehalogenation of alkenyl bromides: a new approach to the synthesis of (E)-alkenes

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The article was received on 15 Jan 2014, accepted on 17 Feb 2014 and first published on 17 Feb 2014


Article type: Communication
DOI: 10.1039/C4CC00345D
Citation: Chem. Commun., 2014,50, 4069-4072
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    Stereospecific hydrodehalogenation of alkenyl bromides: a new approach to the synthesis of (E)-alkenes

    G. Chelucci, Chem. Commun., 2014, 50, 4069
    DOI: 10.1039/C4CC00345D

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