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Issue 41, 2014
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Complexation-induced inversion of helicity by an organic guest in a dynamic molecular propeller based on a tristerephthalamide host with a two-layer structure

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Abstract

A tristerephthalamide host exhibited two helical geometries with (M)- and (P)-helicity, respectively, in terms of the twisting direction of a two-layer structure, and the helical preference switched upon complexation with a ditopic guest. In both uncomplexed and complexed states, the intramolecular transmission of chirality was responsible for the control of helicity.

Graphical abstract: Complexation-induced inversion of helicity by an organic guest in a dynamic molecular propeller based on a tristerephthalamide host with a two-layer structure

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Publication details

The article was received on 15 Jan 2014, accepted on 28 Jan 2014 and first published on 29 Jan 2014


Article type: Communication
DOI: 10.1039/C4CC00323C
Citation: Chem. Commun., 2014,50, 5438-5440
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    Complexation-induced inversion of helicity by an organic guest in a dynamic molecular propeller based on a tristerephthalamide host with a two-layer structure

    R. Katoono, K. Fujiwara and T. Suzuki, Chem. Commun., 2014, 50, 5438
    DOI: 10.1039/C4CC00323C

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