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Issue 21, 2014
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Enantioselective hydroacylation of N-vinylindole-2-carboxaldehydes

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Abstract

We report catalytic, enantioselective intramolecular hydroacylation of N-vinylindole-2-carboxaldehydes. These hydroacylation reactions occur in the presence of a readily accessible rhodium catalyst and form chiral, non-racemic 2,3-dihydro-1H-pyrrolo[1,2-a]indol-1-ones in high yields with excellent enantioselectivities.

Graphical abstract: Enantioselective hydroacylation of N-vinylindole-2-carboxaldehydes

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Publication details

The article was received on 09 Jan 2014, accepted on 24 Jan 2014 and first published on 24 Jan 2014


Article type: Communication
DOI: 10.1039/C4CC00210E
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 2765-2768
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    Enantioselective hydroacylation of N-vinylindole-2-carboxaldehydes

    A. Ghosh and L. M. Stanley, Chem. Commun., 2014, 50, 2765
    DOI: 10.1039/C4CC00210E

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