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Issue 25, 2014
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Direct carboxylation of allylic halides with carbon dioxide in the presence of indium

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Abstract

A highly regioselective indium-mediated allylation of carbon dioxide starting from simple allylic halides (X = I, Br, Cl) has been developed. No transition metal catalyst is needed and an inert atmosphere is not necessary. The reaction tolerates a wide range of synthetically attractive functional groups with a very high branched regioselectivity.

Graphical abstract: Direct carboxylation of allylic halides with carbon dioxide in the presence of indium

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Publication details

The article was received on 08 Jan 2014, accepted on 29 Jan 2014 and first published on 31 Jan 2014


Article type: Communication
DOI: 10.1039/C4CC00148F
Citation: Chem. Commun., 2014,50, 3285-3287
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    Direct carboxylation of allylic halides with carbon dioxide in the presence of indium

    B. Miao and S. Ma, Chem. Commun., 2014, 50, 3285
    DOI: 10.1039/C4CC00148F

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