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Issue 26, 2014
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Highly diastereoselective hydrosilylations of allylic alcohols

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Abstract

The highly syn-selective hydrosilylation of allylic alcohols was developed which, following oxidation, provided 1,3 alcohols containing two contiguous stereocentres. Through judicious choice of silane the complementary anti-selective hydrosilylation was also developed. This protocol was applied to the synthesis of an all syn polyketide stereotriad.

Graphical abstract: Highly diastereoselective hydrosilylations of allylic alcohols

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Publication details

The article was received on 07 Jan 2014, accepted on 11 Feb 2014 and first published on 13 Feb 2014


Article type: Communication
DOI: 10.1039/C4CC00138A
Citation: Chem. Commun., 2014,50, 3501-3504
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    Highly diastereoselective hydrosilylations of allylic alcohols

    M. G. McLaughlin and M. J. Cook, Chem. Commun., 2014, 50, 3501
    DOI: 10.1039/C4CC00138A

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