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Issue 22, 2014
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Synthesis, structure and reactivity of group 4 corrole complexes

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Abstract

A series of early transition metal corrole complexes has been prepared via salt metathesis with the corresponding lithium corrole. Their characterization by single crystal X-ray diffraction, NMR, and absorption spectroscopy is described. Organometallic derivatives of the titanium complex were obtained via treatment of 2 with NaCp* or ClMgCH2SiMe3.

Graphical abstract: Synthesis, structure and reactivity of group 4 corrole complexes

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Publication details

The article was received on 02 Jan 2014, accepted on 30 Jan 2014 and first published on 30 Jan 2014


Article type: Communication
DOI: 10.1039/C4CC00037D
Citation: Chem. Commun., 2014,50, 2922-2924
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    Synthesis, structure and reactivity of group 4 corrole complexes

    R. Padilla, H. L. Buckley, A. L. Ward and J. Arnold, Chem. Commun., 2014, 50, 2922
    DOI: 10.1039/C4CC00037D

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