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Issue 41, 2014
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A supramolecular Co(II)14-metal–organic cube in a hydrogen-bonded network and a Co(II)–organic framework with a flexible methoxy substituent

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Abstract

The reaction of 4,5-dicyano-2-methoxyimidazole (L1) with Co(NO3)2·6H2O under solvothermal conditions in DMF, a MOF, IFP-8 and a hydrogen-bonded network consisting of tetradecanuclear Co(II)14-metal organic cube (1) are achieved. 1 shows the bcu net with 14 cobalt atoms.

Graphical abstract: A supramolecular Co(ii)14-metal–organic cube in a hydrogen-bonded network and a Co(ii)–organic framework with a flexible methoxy substituent

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Publication details

The article was received on 22 Dec 2013, accepted on 26 Mar 2014 and first published on 26 Mar 2014


Article type: Communication
DOI: 10.1039/C3CC49698H
Citation: Chem. Commun., 2014,50, 5441-5443
  • Open access: Creative Commons BY license
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    A supramolecular Co(II)14-metal–organic cube in a hydrogen-bonded network and a Co(II)–organic framework with a flexible methoxy substituent

    S. S. Mondal, A. Bhunia, A. Kelling, U. Schilde, C. Janiak and H. Holdt, Chem. Commun., 2014, 50, 5441
    DOI: 10.1039/C3CC49698H

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