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Issue 31, 2014
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A highly stable MOF with a rod SBU and a tetracarboxylate linker: unusual topology and CO2 adsorption behaviour under ambient conditions

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Abstract

A Mn-based rod metal–organic framework (MOF), ROD-6, with a new lrk net is synthesized. It represents an unusual type of MOF topology containing both a 1-periodic secondary building unit (rod SBU) and a polytopic linker (here 1,3,6,8-tetrakis(p-benzoic acid)pyrene), and also exhibits high stability (up to 485 °C) and unusual CO2 uptake behaviour and selectivity despite the lack of strong interacting sites, demonstrated by the low and increasing heat of adsorption.

Graphical abstract: A highly stable MOF with a rod SBU and a tetracarboxylate linker: unusual topology and CO2 adsorption behaviour under ambient conditions

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Publication details

The article was received on 21 Dec 2013, accepted on 25 Feb 2014 and first published on 25 Feb 2014


Article type: Communication
DOI: 10.1039/C3CC49684H
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 4047-4049
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    A highly stable MOF with a rod SBU and a tetracarboxylate linker: unusual topology and CO2 adsorption behaviour under ambient conditions

    R. Li, M. Li, X. Zhou, D. Li and M. O'Keeffe, Chem. Commun., 2014, 50, 4047
    DOI: 10.1039/C3CC49684H

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