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Issue 28, 2014
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A semiconducting microporous framework of Cd6Ag4(SPh)16 clusters interlinked using rigid and conjugated bipyridines

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Abstract

Ternary supertetrahedral chalcogenolate clusters were interlinked with bipyridines into a microporous semiconducting framework with properties qualitatively different from those of the original clusters. Both the framework and the clusters were effective photocatalysts, and rapidly degraded the dye rhodamine B.

Graphical abstract: A semiconducting microporous framework of Cd6Ag4(SPh)16 clusters interlinked using rigid and conjugated bipyridines

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Publication details

The article was received on 20 Dec 2013, accepted on 11 Feb 2014 and first published on 12 Feb 2014


Article type: Communication
DOI: 10.1039/C3CC49660K
Citation: Chem. Commun., 2014,50, 3710-3712
  • Open access: Creative Commons BY-NC license
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    A semiconducting microporous framework of Cd6Ag4(SPh)16 clusters interlinked using rigid and conjugated bipyridines

    C. Xu, N. Hedin, H. Shi and Q. Zhang, Chem. Commun., 2014, 50, 3710
    DOI: 10.1039/C3CC49660K

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