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Issue 18, 2014
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Oxovanadium(V)-induced diastereoselective oxidative homocoupling of boron enolates

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Abstract

Oxovanadium(V)-induced dl-selective oxidative coupling of (Z)-boron enolate was demonstrated to give the corresponding 2,3-disubstituted 1,4-diketone in a good yield. High selectivity (up to 94 : 6) was attained when the reaction was performed with VO(OPr-i)2Cl at −30 °C.

Graphical abstract: Oxovanadium(v)-induced diastereoselective oxidative homocoupling of boron enolates

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Publication details

The article was received on 19 Dec 2013, accepted on 30 Dec 2013 and first published on 17 Jan 2014


Article type: Communication
DOI: 10.1039/C3CC49624D
Citation: Chem. Commun., 2014,50, 2279-2281
  • Open access: Creative Commons BY-NC license
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    Oxovanadium(V)-induced diastereoselective oxidative homocoupling of boron enolates

    T. Amaya, T. Masuda, Y. Maegawa and T. Hirao, Chem. Commun., 2014, 50, 2279
    DOI: 10.1039/C3CC49624D

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