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Issue 25, 2014
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The synergistic effect of nanoporous AuPd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones

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Abstract

The nanoporous AuPd (AuPdNPore) alloy catalyst showed superior chemoselectivity and high catalytic activity for the direct 1,4-hydrosilylation of the conjugated cyclic enones with hydrosilane in comparison with the monometallic nanoporous Au and Pd catalysts. The enhanced catalytic properties of AuPdNPore arise mainly from the nanoporous structure and the synergistic effect of the AuPd alloy.

Graphical abstract: The synergistic effect of nanoporous AuPd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones

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Publication details

The article was received on 16 Dec 2013, accepted on 10 Feb 2014 and first published on 10 Feb 2014


Article type: Communication
DOI: 10.1039/C3CC49524H
Citation: Chem. Commun., 2014,50, 3344-3346
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    The synergistic effect of nanoporous AuPd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones

    Q. Chen, S. Tanaka, T. Fujita, L. Chen, T. Minato, Y. Ishikawa, M. Chen, N. Asao, Y. Yamamoto and T. Jin, Chem. Commun., 2014, 50, 3344
    DOI: 10.1039/C3CC49524H

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