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Issue 31, 2014
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The corrole and ferrocene marriage: 5,10,15-triferrocenylcorrolato Cu

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Abstract

Two synthetic routes have been defined for the preparation of a 5,10,15-triferrocenylcorrole Cu derivative. This complex has been characterized and the preliminary electrochemical investigation shows a strong interaction among the corrole and meso ferrocenyl substituents. The results obtained suggest that peculiar properties are gained by combining the eccentric characteristics of ferrocenyl substitution with the corrole macrocycle.

Graphical abstract: The corrole and ferrocene marriage: 5,10,15-triferrocenylcorrolato Cu

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Publication details

The article was received on 11 Dec 2013, accepted on 23 Jan 2014 and first published on 23 Jan 2014


Article type: Communication
DOI: 10.1039/C3CC49416K
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 4076-4078
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    The corrole and ferrocene marriage: 5,10,15-triferrocenylcorrolato Cu

    G. Pomarico, A. Vecchi, F. Mandoj, O. Bortolini, D. O. Cicero, P. Galloni and R. Paolesse, Chem. Commun., 2014, 50, 4076
    DOI: 10.1039/C3CC49416K

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