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Issue 17, 2014
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Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles

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Abstract

The one-pot syntheses of a series of dimeric and trimeric selenotungstates based on the [Se2W12O46]12− unit are presented alongside the structure of the tetrameric [Se8W48O176]32− wheel. Mass spectrometry has probed the stability of these clusters whilst their electronic structure has been contrasted to their known phosphotungstate analogues.

Graphical abstract: Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles

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Publication details

The article was received on 06 Dec 2013, accepted on 03 Jan 2014 and first published on 06 Jan 2014


Article type: Communication
DOI: 10.1039/C3CC49293A
Citation: Chem. Commun., 2014,50, 2155-2157
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    Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles

    J. M. Cameron, J. Gao, L. Vilà-Nadal, D. Long and L. Cronin, Chem. Commun., 2014, 50, 2155
    DOI: 10.1039/C3CC49293A

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