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Issue 22, 2014
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Observation of allylic rearrangement in water-rich reaction

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Abstract

Allylic rearrangement or the migration of a double bond from its original position in the carbon skeleton to an adjacent site was observed when 3,4,5,6-tetrahydrophthalate was hydrolyzed in a basic solution and in the presence of Co(II) and Mn(II) under hydrothermal conditions.

Graphical abstract: Observation of allylic rearrangement in water-rich reaction

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Publication details

The article was received on 06 Dec 2013, accepted on 23 Jan 2014 and first published on 24 Jan 2014


Article type: Communication
DOI: 10.1039/C3CC49287G
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 2910-2912
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    Observation of allylic rearrangement in water-rich reaction

    Y. Pang, X. Hou, L. Qin, C. Wu, W. Xue, Y. Zheng, Z. Zheng and X. Chen, Chem. Commun., 2014, 50, 2910
    DOI: 10.1039/C3CC49287G

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