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Issue 20, 2014
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Zn-BTC MOFs with active metal sites synthesized via a structure-directing approach for highly efficient carbon conversion

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Abstract

Three zinc-trimesic acid (Zn-BTC) MOFs, BIT-101, BIT-102 and BIT-103, have been synthesized via a structure-directing strategy. Interestingly, BIT-102 and -103 exhibit extraordinary catalytic performance (up to Conv. 100% and Sele. 95.2%) in the cycloaddition of CO2 under solvent- and halogen-free conditions without any additives or co-catalysts.

Graphical abstract: Zn-BTC MOFs with active metal sites synthesized via a structure-directing approach for highly efficient carbon conversion

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Publication details

The article was received on 03 Dec 2013, accepted on 10 Jan 2014 and first published on 10 Jan 2014


Article type: Communication
DOI: 10.1039/C3CC49187K
Citation: Chem. Commun., 2014,50, 2624-2627
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    Zn-BTC MOFs with active metal sites synthesized via a structure-directing approach for highly efficient carbon conversion

    X. Huang, Y. Chen, Z. Lin, X. Ren, Y. Song, Z. Xu, X. Dong, X. Li, C. Hu and B. Wang, Chem. Commun., 2014, 50, 2624
    DOI: 10.1039/C3CC49187K

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