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Issue 22, 2014
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Photo- and thermo-induced spin crossover in a cyanide-bridged {MoV2FeII2} rhombus molecule

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Abstract

The self-assembly of [MoV(CN)8]3− and [FeII(bik)2(S)2]2+ affords a cyanide-bridged {MoV2FeII2} rhombus molecule that shows photomagnetic effect under laser light irradiation at low temperature and exhibits thermo-induced spin crossover near ambient temperature.

Graphical abstract: Photo- and thermo-induced spin crossover in a cyanide-bridged {MoV2FeII2} rhombus molecule

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Publication details

The article was received on 02 Dec 2013, accepted on 22 Jan 2014 and first published on 23 Jan 2014


Article type: Communication
DOI: 10.1039/C3CC49164A
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 2893-2895
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    Photo- and thermo-induced spin crossover in a cyanide-bridged {MoV2FeII2} rhombus molecule

    A. Mondal, Y. Li, L. Chamoreau, M. Seuleiman, L. Rechignat, A. Bousseksou, M. Boillot and R. Lescouëzec, Chem. Commun., 2014, 50, 2893
    DOI: 10.1039/C3CC49164A

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