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Issue 35, 2014
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Catalytic activation of OKO zeolite with intersecting pores of 10- and 12-membered rings using atomic layer deposition of aluminium

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Abstract

Tetrahedral framework aluminium was introduced in all-silica zeolite -COK-14 using Atomic Layer Deposition (ALD) involving alternating exposure to trimethylaluminium and water vapour. The modification causes permanent conversion of the originally interrupted framework of -COK-14 to a fully connected OKO type framework, and generates catalytic activity in the acid catalysed hydrocarbon conversion reaction.

Graphical abstract: Catalytic activation of OKO zeolite with intersecting pores of 10- and 12-membered rings using atomic layer deposition of aluminium

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Publication details

The article was received on 26 Nov 2013, accepted on 06 Mar 2014 and first published on 12 Mar 2014


Article type: Communication
DOI: 10.1039/C3CC49028A
Citation: Chem. Commun., 2014,50, 4610-4612
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    Catalytic activation of OKO zeolite with intersecting pores of 10- and 12-membered rings using atomic layer deposition of aluminium

    E. Verheyen, S. Pulinthanathu Sree, K. Thomas, J. Dendooven, M. De Prins, G. Vanbutsele, E. Breynaert, J.-P. Gilson, C. E. A. Kirschhock, C. Detavernier and J. A. Martens, Chem. Commun., 2014, 50, 4610
    DOI: 10.1039/C3CC49028A

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