Issue 19, 2014
From the journal:

Chemical Communications

Unexpected structural motifs in diamine coordination compounds with allyllithium†

Prisca K. Eckert,a   Barbara Schnuraa  and  Carsten Strohmann*a  

* Corresponding authors

a TU Dortmund, Anorganische Chemie, Otto-Hahn-Str. 6, 44149 Dortmund, Germany
E-mail: mail@carsten-strohmann.de
Fax: +49 231 755 7062
Tel: +49 231 755 3807

Abstract

New diamine coordination compounds with phenyllithium and allyllithium are presented. One of them is the first diamine complex containing two different, simple organolithium reagents. The formation of this unexpected compound is explained using quantum chemical calculations.

Graphical abstract: Unexpected structural motifs in diamine coordination compounds with allyllithium

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Article information

DOI
https://doi.org/10.1039/C3CC48873J
Article type
Communication
Submitted
20 Nov 2013
Accepted
23 Dec 2013
First published
02 Jan 2014

Chem. Commun., 2014,50, 2532-2534

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Unexpected structural motifs in diamine coordination compounds with allyllithium

P. K. Eckert, B. Schnura and C. Strohmann, Chem. Commun., 2014, 50, 2532 DOI: 10.1039/C3CC48873J

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