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Issue 11, 2014
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Stabilisation of μ-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands

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Abstract

The spectroscopic characterisation of the (μ-1,2-peroxido)diiron(III) species formed transiently upon reaction of [Fe(II)(NN)3]2+ complexes with H2O2 by UV/vis absorption and resonance Raman spectroscopy is reported. The intermediacy of such species in the disproportionation of H2O2 is demonstrated.

Graphical abstract: Stabilisation of μ-peroxido-bridged Fe(iii) intermediates with non-symmetric bidentate N-donor ligands

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Publication details

The article was received on 25 Oct 2013, accepted on 25 Nov 2013 and first published on 26 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC48196D
Citation: Chem. Commun., 2014,50, 1326-1329
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    Stabilisation of μ-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands

    J. S. Pap, A. Draksharapu, M. Giorgi, W. R. Browne, J. Kaizer and G. Speier, Chem. Commun., 2014, 50, 1326
    DOI: 10.1039/C3CC48196D

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