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Issue 9, 2014
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One-pot synthesis of D-glucosamine and chitobiosyl building blocks catalyzed by triflic acid on molecular sieves

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Abstract

Combining triflic acid-catalyzed acetalation, benzylation, reductive ring opening of benzylidene acetal and glycosylation in one-pot transformations leads to a wide range of D-glucosamine building blocks for assembling oligomers.

Graphical abstract: One-pot synthesis of d-glucosamine and chitobiosyl building blocks catalyzed by triflic acid on molecular sieves

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Publication details

The article was received on 21 Oct 2013, accepted on 15 Nov 2013 and first published on 15 Nov 2013


Article type: Communication
DOI: 10.1039/C3CC48078J
Citation: Chem. Commun., 2014,50, 1067-1069
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    One-pot synthesis of D-glucosamine and chitobiosyl building blocks catalyzed by triflic acid on molecular sieves

    G. Despras, D. Urban, B. Vauzeilles and J. Beau, Chem. Commun., 2014, 50, 1067
    DOI: 10.1039/C3CC48078J

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